刘滇生

1953年5月出生，博士生导师，现任山西大学副校长。 1973年经推荐上山西大学化学系，78年考入山西大学物理化学专业研究生，81年毕业后留校任教。 1989年获Sussex大学邵逸夫奖学金赴英国攻读博士学位，师从英国皇家院士、道尔顿化学学会主席Lappert教授，从事有机金属化学、结构化学的研究。 93年5月获博士学位，后在大学继续博士后工作，并在香港中文大学进行为期一年多的合作研究。96年回校工作，先后担任化学系主任、校长助理、山西大学副校长等职。 在国外刊物上发表了多篇高水平论文，申请了三项荷兰专利，回国后建立了具有国内一流水平的金属有机实验室，先后承担了国家教育部归国人员基金项目和南开大学国家重点实验室项目，目前承担着一项国家基金项目和两项省级科研基金项目。 主要论文(1993~2005)： 1. A convenient route to silyl linked bis(amidinate) ligands and synthesis of group(I) metal derivatives Sheng-Di Bai, Jian-Ping Guo and Dian-Sheng Liu* Dalton Trans., 2006, 2244-2250 2. 2-胺基-6-甲基吡啶金属有机化合 物的合成与结构 郗芳，陈霞，刘滇生，第九届全国络合催化学术讨论会，2005. 10， P222 3. 桥联吡啶金属化合物的合成及结构研究. 陈 霞，郗芳，李文叶，刘滇生 有机化学，2005，25，599. 4. 新型桥联双氨基脒基与环合环已二胺的合成 胡静花，李剑峰，黄淑萍 ，刘滇生 山西大学学报,2004,27(5),111-114 5. 一种β－二亚胺钴配合物的合成与结构研究 张林卿，黄淑萍，刘滇生 山西大学学报,2003， 26（4），324－326 6. 有机锂化 合物催化合成均三嗪 李敏，黄淑萍，刘滇生，李思殿, 化学研究与应用,2003.12.Vol.15,Nol.16 7. Synthesis and structures of the chelating diamido zirconium and hafnium compounds Junsheng Hao, Xuehong Wei, Shuping Huang, Jianping Guo and Diansheng Liu* Applied Organometallic Chemistry, 2005,19(9), 1010-1014 8. Chain lithium complexes supported with ?-diketiminate ligands containing pyridyl on the carbon framework. Xia Chen, Li Wang, Jian-Ping Guo, Shu-Ping Huang and Dian-Sheng Liu*, Mendeleev Commun., 2005, 15(4), 160-161. 9. Reactions of Bis(silyl-substituted) Methyllithium with α-Hydrogen-free Nitriles into 1,3,5-Triazines Xia Chen, Sheng-Di Bai, Li Wang, and Dian-Sheng Liu*, heterocyclics, 2005, 65(6), 1425-1430. 10. 氧桥双β-二亚胺钴配合物的合成及结构 陈霞，魏学红，郭建平，刘滇生 无 机化学学报，2005，21，519-522. 11. catena-Poly [lithium(I)-μ-1-tert-butyl-3-(3-pyridyl)-N,N'-bis(trimethylsilyl)propane-1, 3-diiminato] Xia Chen, LiWang, Jian-Ping Guo, Shu-Ping Huang and Dian-Sheng Liu Acta Cryst. (2005). E61, m574–m576 12. β-二亚胺钴配合物的合成及结构 陈霞，郭 建平， 刘滇生 中国化学会第十三届金属有机化学学术讨论会 2004.10. P54 13. Ph2PCH(SiMe3)2的合成及晶体结构分析 王莉，陈霞 ，黄淑萍，刘滇生山西大学学报，2004, 27, 2 14. 4- tert-Butyl-2-(4-pyridyl)-N,N-?-bis (trimethylsilyl)propane-1,3-diimine Xia Chen, LiWang, Shu-Ping Huang and Dian-Sheng Liu Acta Cryst., 2004, E60, o473–o475 15. [Benzylbis(dimethylamino)methylsilyl-C,N] (N,N,N,N-tetramethylethylenediamine-N,N)lithium(I) He-Ping Shi, Dian-Sheng Liu and Shu-Ping Huang Acta Cryst. 2004，C 60, m107–m109 16. (1 R,2 R)-(–)-Bis[ μ4-1-{[1,1-dimethyl-2-(trimethylsilyl)amidino]amino}-2- ({1,1-dimethyl-2-[1,1-dimethyl-2-(trimethylsilyl)amidino]-amidino}amino)cyclohexane] tetralithium(I) Jing-Hua Hu, Hong-Bo Tong, Jian-Feng Li, Shu-Ping Huang and Dian-Sheng Liu Acta Cryst., 2004, C60, m272–m274 17. The Synthesis and Characterization of Silica-Zirconia Aerogels Zhi- Gang Wu, Yong-Xiang Zhao, Dian-Sheng Liu Microporous and Mesoporous Material, 2004, 68(1-3), 127-132 18. A New Method for Preparing Ti-Si Mixed Oxides Lin Ping Xu, Yong Xiang Zhao, Zhi Gang Wu, Dian Sheng Liu Chinese Chemical Letter, 2003, 14(11),1159-1162 19. Preparation of Zirconia Aerogel by Heating of Alcohol-Aqueous Salt Solution Z.-G. Wu, Y.-X. Zhao, D.-S. Liu Journal of Non-Crystalline Solids, 2003, 330(1- 3), 274-277 38．[Benzyldimethyl(dimethylamino)silyl-C,N]( N,N,N,N-tetramethylenediamine- N,N)lithium(I) He-Ping Shi, Dian-Sheng Liu and Shu-Ping Huang Acta Cryst，2003，E59, m319–m321 ************* 21. [(1-tert-Butyl-2- phenylvinylamino)(dimethylamino)dimethylsilyl-N,N] ( N,N,N,N-tetramethylenediamine-_2 N,N) lithium(I) He-Ping Shi, Dian-Sheng Liu and Shu-Ping Huang Acta Cryst，2003，E59, m339– m341 22. TiIV Complexes with Novel, Chiral, Tridentate Amido-Amidinate or Monoanionic, Didentate Amidinate Ligands Jian-Feng Li, Shu-Ping Huang, Lin-Hong Weng, and Dian-Sheng Liu Eur. J. Inorg. Chem. 2003. 810-813 23. Synthesis and crystal structures of novel b-Diketiminato-lithium, iron, cobalt, nickel, zirconium complexes and their catalytical behaviors in polymerization of ethylene Mei-Su Zhou, Shu-Ping Huang, Lin-Hong Weng, Wen-Hua Sun, Dian-Sheng Liu J. Organomet. Chem. 2003，665， 237-245 24. Syntheses and structures of structurally diverse potassium b-Diketiminates derived from the ligand [{N(SiMe3)C(Ph)}2CH] Peter B. Hitchcock , Michael F. Lappert, Dian-Sheng Liu and Rafael Sablong Chem. Commun., 2002, 1920-1921 25. Addition Reactions of Bis(trimethylsilyl)methyl- and 1-Azaallyl- lithium with Cyanoamines into Triazines or b-Diketiminatolithium Compounds Xia Chen, Chenxia Du, Jianping Guo, Xue-hong Wei, Dian-Sheng Liu J. Organomet. Chem. 2002，655， 89 -95 26. 由6-氨基取代富烯合成二茂 锆络合物及其结构研究 白生弟、原欣亮、杜晨霞、刘滇生 高等学校化学学报， 2002,23 （2）:416-418 27. 顺丁烯二酸酐在NiO/SiO2催化剂上液相加氢合成丁二酸酐和γ-丁内酯的研究 赵永祥、武志刚、许临萍、刘滇生、徐贤伦 化学学报, 已接受 28. Synthesis and Structures of Novel Chiral Lithium Amidinates and Mono-and Di-lithium (1R, 2R)-(-)-1,2-(NHSiMe3)-Cyclohexane Jian-Feng Li, Lin-Hong Weng, Xue-hong Wei, Dian-Sheng Liu J. Chem. Soc., Dalton Trans., 2002 ，1401-1405 29. 后处理条件对NiO/SiO2气凝胶催化剂顺酐选择加氢性能的影响 赵永祥、武志刚、许临萍 、刘滇生、徐贤伦 天然气化工，2001，26(6):8-11 30. NiO/SiO2气凝胶催化剂性能研究：Ⅱ顺酐合成丁二酸酐和γ-丁内酯的工 艺条件 赵永祥、武志刚、王永钊、许临萍、刘滇生、徐贤伦 燃料化学学报，2001，29：182-184 31. NiO/SiO2气凝胶催化剂 性能研究：Ⅰ镍含量的影响 赵永祥、武志刚、许临萍、王永钊、刘滇生、徐贤伦 燃料化学学报， 2001，29：178-181 32. 溶胶-凝胶法制备NiO/SiO2催化剂研究 赵永祥、武志 刚、张临卿、刘滇生、徐贤伦 分子催化，2001，15（5）：370-373 33. Reaction of LiCHR2 and related lithium alkyls with α- H free nitriles and the crystal structures of eleven representative lithium 1,3-diazaallyls, 1-azaallyls and β-diketiminates Peter B. Hitchcock, Michael F. Lappert, Marcus Layh, Dian-Sheng Liu, Rafael Sablong and Tian Shun J. Chem. Soc., Dalton Trans., 2000, 2301-2312 34. Synthesis and structures of novel phenyl-bridged bis(1-aza-allyl) alkali-metal compounds Wing-Por Leung, Hui Cheng, Dian-Sheng Liu, Qi-Guang Wang, and Thomas C.W. Mark Organometallics, 2000, 19, 3001-3007 35. Synthesis and structures of the crystalline heavier alkali metal alkyls: x-ray structures of [K(- R){O(Me)But}], [(pmdeta) K(-R)K(-R)2K(-R)K(pmdeta)], and [ Cs(-R)(tmeda)](R=CH(SiMe3)2) W.Marco Boesveld, Peter B. Hitchcock, Michael F. Lappert, Dian-Sheng Liu and Tian Shun Organometallics, 2000, 19, 4030-4035 36. 由富烯配体合成茂金属化合物的研究 白生弟， 魏学红，原欣亮， 刘滇生 有机化学， 2000，21（11）：1040-1045 37. Study on the Synthesis and Structures of b- Diketiminatometal Complexes Xia Chen, Wei Xuehong, Liu Diansheng 5th International Symposium on Organo-Metals Metal Complexes and Catalysis (OMC-V) August 21-24,2000, Baoding, China, P64 38. Synthesis and characterization of trizine and β-diketiminato-lithium Xia Chen, Shengdi Bai and Diansheng Liu The 10th international symposium on fine chemistry and functional polymers, Sept. 20-23, 2000. Jinan, China. P77 39. Study on the synthesis and structure of [N(SiMe3)C(But)CH(SiMe3)]2 Xia Chen, Xuehong Wei, Jianping Guo and Diansheng liu The 5th international symposium on organo- metal complexes and catalysis ( OMC-Ⅴ). August 21-24,2000. Baoding, China. P46 40. Metal complexes containing novel β-diketiminato ligands Laurence Bourget-Merle, James D. Farwell, Peter B. Hitchcock, Michael F. Lappert, Dian-Sheng Liu The 19th IUPAC International Conference on Organometallic Chemistry. July 23-28, 2000, Shanghai, China. O036 41. β-二亚胺镍（Ⅱ）配合物的合成及其结 构研究 魏学红， 郭建平，刘滇生 无机化学学报， 1999, 15: 400 42. Intermolecular NMe2H elimination and fulvene coupling leading to novel allyl-bridged zirconocene and hafnocene complexes Sheng-Di Bai, Xue-Hong Wei, Jian-Ping Guo, Dian-Sheng Liu and Zhong-Yuan Zhou Angew.Chem.Int.Ed.1999, 38(13/14):1926-1928 43. Reactions of silylallyl-lithium or potassium compounds with ButCN; synthesis and structures of [M{N(SiMe2R)C(But)(CH)3SiMe2But}] [M=Li(tmen), R=Me; or M=K, R=But], [Li{N(SiMe3)C(But)CCHC(SiMe3)(CH2)2CH2]}](tmen=Me2NCH2CH2NMe 2) Peter B. Hitchcock, Michael F. Lappert, Wing-Por Leung, Dian-Sheng Liu, Thomas C. W. Mak and Zhong- Xia Wang J. Chem. Soc. Dalton Trans., 1999,1263-1269 44. Synthesis and structures of some silylallyl-lithium or potassium complexes Peter B. Hitchcock, Michael F. Lappert, Wing -Por Leung, Dian-Sheng Liu, Thomas C. W. Mak and Zhong-Xia Wang J. Chem. Soc. Dalton Trans., 1999, 1257-1262 45. Synthesis and characterization of trimrthylsilylmethyl-, bis (trimethylsilyl)methyl-, and silyl-substituted cyclopentadienes and their alkali metal complexes Michael A. Edelman, Peter B. Hitchcock, Michael F. Lappert, Dian-Sheng Liu and Shun Tian J. Organomet. Chem. 1998, 550, 397-408 46. The chemistry of 1-aza-allyl-and β-diketiminato- metal complexes: a review Peter B. Hitchcock, Jin Hu, Michael F. Lappert, Marcus Layh, Dian -Sheng Liu, John R. Stevern and Tian Shun Angles de Quimica Int. Ed. 1996, 92: 186-190 47. Recent studies on metal and metalloid bis (trimethylsilyl)-methyls and the transformation of the bis(trimethylsilyl)-methyl into the aza-allyl and β-diketinimato ligands Michael F. Lappert and Dian-Sheng Liu J. Organomet. Chem., 1995, 500,203-217 48. Preparation, spectra and x-ray structure of an archetypal coordination compound [BCl3(NH3)] and its thermolysisAnthony G. Avent, Peter B. Hitchcock, Michael F. Lappert, Dian-Sheng Liu, Gerard Mignani, Christophe Richard and eric Roche J. Chem.Soc., Chem. Commun., 1995, pps.855-856 49. New organometallic compounds, process for preparation of those, and processes for polymerising unsaturated hydrocarbons using said organometallic compounds as catalysts, as well as new intermediatees and catalyst-preparation荷兰专利，申请号9500085 50. Transformation of the bis (trimethylsilyl)methyl into a 1,3-diaza-allyl ligand. Synthesis and crystal structures of [K{N(R )C(Ar)NC(Ar)CHR}(NCAr)]2 and [{UCl (μ-Cl)(L)(NR)}2][UCl2(L)(L’)]2[R=SiMe3; Ar=C6H3Me2-2,5; L=N(R)C(Ph)C(H)C(Ph)NR; L’=N(R )C(Ph)NC(Ph)CHR]Peter B. Hitchcock, Michael F. Lappert and Dian-Sheng LiuJournal of Organometallic Chemistry. 1995,488, pps. 241-248 51. Ligand redistribution reactions as a route to cyclopentadienyl- or 1-aza-allylzirconium (Ⅳ) trichlorides and the x-ray structures of [{Zr(LL’)Cl2(μ-Cl)}2] and [ Zr(LL’)2Cl2] [LL’ =N(R)C(But)CHR, R=SiMe3]Peter B. Hitchcock, Michael F. Lappert, Dian-Sheng Liu and Evelyn J. RyanPolyhedron. 1995 ,14(19): 2745-2752 52. Some new silicotropic rearrangements(Chapter)P.B. Hitchcock, M.F. Lappert, D.-S. Liu and S. TianCh. 21 in ‘ Progress in Organosilicon Chemistry’. Eds. B.Marciniec and J.Chojnowski Gordon and Breach, Basel 1995. Pps.345-359 53. "New organometallic compounds and process for polymerising olefins using said organometallic compounds as catalysts", 荷兰专 利，申请号9401515 54. "New organometallic compounds and process for polymerising olefins using said organometallic compounds as catalysts", 荷兰专利，申请号9400919 55. ransformation of the Bis(trimethylsilyl)methyl into Aza-allyl and b-Diketinimato Ligands; the X-Ray Structure of and (R = SiMe3)P. B. Hitchcock, M. F. Lappert and D. S. Liu J.Chem.Soc., Chem.Commun., 1994.pps.2637-2638 56. Transformation of the bis(trimethylsilyl) methyl into a β-diketinimato ligand; the X-ray structure of [Li(L’L’)]2, SnCl(Me)2 (L’L’) and SnCl(Me)2(LL), [ L’L’=N(R)C(Ph)C(H)C(Ph)NR, LL=N(H)C(Ph)C(H)C(Ph)NH, R=SiMe3]Peter B. Hitchcock, Michael F. Lappert and Diansheng LiuJ.Chem.Soc., Chem.Commun., 1994. p1699-1700 57. Synthesis and structures of the heavier alkali metal alkyls; the X-ray structures of [Na(μ-R)]∞ and [Rb(μ-R)(pmdeta)]2 [R=CH(SiMe3)2, pmdeta=(Me2NCH2CH2)2NMe] Peter B. Hitchcock, Michael F. Lappert, Wing-Por Leung, Liu Diansheng and Tian ShunJ.Chem.Soc., Chem.Commun., 1993. No. 18. P1386-1387 主要科研项目： 1.山东大学,横向科研,资助额:1万元,2005-3,排名:1 2.1,4-丁炔二醇催化合成1,4-丁二醇的核心技术--二段加氢催化剂的国产化研究开发,国家“863”计划,资助额:100万元,2005-6,排名:3 3.常温下催化消除一氧化碳催化剂的研制与应用,山西省科委攻关项目,资助额:15万元,2003-7,排名:2 4.用于养殖水体净化的微生物固化板研究,山西省教委应用开发项目,资助额:3万元,2003-12,排名:2 5.手性脒基金属有机化合物的合成、表征与应用,山西省回国留学基金,资助额:4万元,2003-12,排名:1 6.亚胺金属有机化合物的合成及其在催化反应中的应用2004,国家自然科学基金,资助额:6万元,2004-4,排名:1 7.北方盐碱养殖水体生物酸碱调节技术的开发及其应用,山西省科委攻关项目,资助额:10万元,2004-6,排名:2 8.B-二亚胺金属化合物合成及结构研究,,资助额:2.5万元,2000-7,排名:4 9.制造CO2气体保护焊丝的拉丝油研究,,资助额:10万元,2000-10,排名:2 10.溶胶-凝胶法制备无机/有机杂化材料,,资助额:5万元,2000-12,排名:1 11.顺酐催化加氢制丁二酸酐和r-丁内酯,,资助额:10万元,2001-6,排名:1 12.高压催化加氢法合成三羟甲基丙烷的研究,,资助额:6万元,2002-1,排名:1 13.蓄电池消氢器的研制与开发,,资助额:6万元,2002-1,排名:1 14.亚胺金属有机化合物的合成及其在催化反应中的应用,,资助额:20万元,2001-10,排名:1 15.常温下催化消除一氧化碳催化剂的工业试验,,资助额:15万元,2003-6,排名:2 16.新型可生物降解三羟甲基丙烷聚酯增塑剂的催化合成,山西省科委攻关项目,资助额:15万元,2005-6,排名:2 17.绿色生态种植促果叶面喷施剂的开发与应用,山西省科委攻关项目,资助额:15万元,2005-6,排名:1 18.硒代蛋氨酸的合成工艺研究,山西省教委应用开发项目,资助额:5万元,2005-6,排名:2 19.手性DACH胺基-脒基化合物的合成与结构-性能研,国家自然科学基金,资助额:23万元,2004-10,排名:1 获奖、鉴定、专利情况： 获奖 1.新型光敏水解褪色材料的研究及应用,国家技术发明二等奖,等级:二,2004-12,排名:2 鉴定 2.新型绿色农产品栽培技术的研究与应用,鉴定单位:山西省科技厅,结论:国内领先,2004-3,排名:1 3.去除热轧不锈钢氧化皮,鉴定单位:省科技厅,结论:国际先进,2005-8,排名:4 专利 4.一种高比表面、高分散度硅钛复合氧化物的制备方法,专利类型:发明,专利号:130077,2003-11,排名:3 5.2,4,6-三取代-均三嗪化合物及其合成方法,专利类型:发明,专利号:147299,2004-3,排名:3 6.高比表面SIO2-Al2O3复合氧化物的制备,专利类型:发明,专利号:167381,2004-5,排名:2 7.一种β-二亚胺金属配合物及其合成方法,专利类型:发明,专利号:169725,2004-5,排名:4 8.用于拉拔金属线材的水基润滑剂及其制备方法,专利类型:发明,专利号:213974,2005-6,排名:2 荷兰专利： Name: Specs & Biospecs B.V.： Country: The Netherlands： Title: Nieuwe organometaalverbindingen, werkwijzen ter bereiding daarvan en weikwijzen voor het polymeriseren van onverzadigde koolwaterstoffen onder toepassing van deze organometaalverbindingen als katalysatoren, alsmede nieuwe tussenprodukten en katalysator-preparaten： Number: 9500085： ： 2. Naam: Specs & Biospecs B.V.： Land: Netherland： Titel: Nieuwe organometaalverbindingen en werkwijzw voor het polymeiseren van alkenen onder toepassing van deze organometaalverbindingen als katalysatorenf： Nummer: 94.01515： Indieningsdatum: 19 September 1994： ： 3. Naam: Specs B.V.： Land: Netherland： Titel: Nieuwe organometaalverbindingen en werkwijzw voor het polymeiseren van alkenen onder toepassing van deze organometaalverbindingen als katalysatorenf： Nummer: 94.00919： Indieningsdatum: 7 Juni 1994： ： 中国发明专利：： 1. 2，4，6-三取代-均三嗪化合物及其合成方法： 陈霞、白生弟、刘滇生等： 中国发明专利，2004.3 专利号：01120415.X： 2. 一种β-二亚胺金属配合物及其合成方法： 周梅素、陈霞、魏学红、 刘滇生： 中国发明专利，2004.7, 专利号：01122341.3： 3. 高比表面SiO2-Al2O3复合氧化物的制备方法： 赵永祥、武志刚、许临萍、张临卿、王永钊、刘滇生： 中国发明专利，申请号：01122340.5： ： 获奖：国家技术发明二等奖，2005.1.8： 项目名称：新型光敏水解褪色材料的研究及应用： 证书号：2004-F-211-2-01-02：