刘宾元

刘宾元，博士，教授。1970年10月出生于山东省新泰市。教育部科技发展中心科研基金和科技奖励评审专家库。 研究方向：专用聚烯烃材料聚合催化剂的研发及其聚烯烃材料的共混、利用二氧化碳在内的可再生资源合成高分子材料和包括耐高温聚芳醚酮和超低介电常数在内的高性能工程塑料的研发。 一、学历 1992.09-1994.07 泰安师范专科学校 化学系 1994.09-1996.07 学士 曲阜师范大学 化学系 1996.09-1998.10 硕士 中科院长春应化所 无机化学 1998.10-2001.12 博士 中科院长春应化所 高分子化学与物理 工作经历 2002.02-2003.03 博士后 韩国汉城国立大学 分子科学与工程系 2001.12-2003.03 助理研究员 中科院长春应用化学研究所 2003.03-2008.12 副教授 河北工业大学 高分子科学与工程系 2006.7-2007.07 访问学者 韩国釜山国立大学 高分子科学与工程系 2008.12- 教授 河北工业大学 高分子科学与工程系 二、科研项目 1. 河北工业大学校引进人才资助项目, “二氧化碳与环氧化合物共聚新型催化剂的分子设计及活性研究” （2003年，负责人） 2. 清华大学核能与新能源技术研究院, （横向）“超微颗粒的稳定化及在有机-无机复合材料中的应用研究”（2004-2005） 3. 清华大学核能与新能源技术研究院, （横向）“氧化锆纳米复合材料的研究”（2005-2006，负责人） 4. 教育部留学人员科研基金, “表面原子转移自由基聚合制备具有核壳结构的纳米复合材料的研究”（2005， 负责人） 5. 国家自然科学基金, “不含氟的低介电常数纳米孔聚降冰片烯的合成及性能研究”（50403013）（2005-2007，负责人） 6. 河北省科技支撑计划, “聚丁烯-1制备专用Ziegler-Natta催化剂的开发”（09215110D）（2009-2011，负责人） 7. 中国石油天然气股份有限公司科学创新研究与技术开发项目, 可调控PE分子量分布的改性钛-镁催化剂研究，（2009-2010，负责人） 8. 天津市自然科学基金, “酰亚胺基聚降冰片烯低介电常数材料的制备及性能的研究”（08JCYBJC02500）（2008－2010，负责人） 9. 河北省自然科学基金, “功能降冰片烯加成类聚合物的合成与性能研究”（B2008000009）（2008－2010， 负责人） 10. 国家自然科学基金, “单一主催化剂多米诺催化乙烯共聚合成LLDPE研究”（50573018）（2006-2008，第2） 11. 中国石油天然气股份有限公司科学创新研究与技术开发项目, “聚丁烯-1树脂合成技术开发” （2008D5006-05-02）（2009-2010，第2） 12. 教育部科学技术研究重点项目, “LTL型沸石单层薄膜的定向构筑及其应用” （2008-2010，第3） 13. 河北省科学技术研究与发展计划, “稀土/桥联聚倍半硅氧烷的超分子构筑和发光性能”（08965110D） (2008-2010, 第2) 14. 中国石油天然气股份有限公司科学研究与技术开发项目, “透明易加工LLDPE聚合中试研究” （0604A18-11）（2007-2008，第4） 三、文章与专利 专利 1. 刘宾元, 田春英, 张莉 用于二氧化碳与环氧化合物共聚的催化剂及其制备方法，专利公开号：CN 1715307A（授权，ZL2005 1 0013808.4） 2. 刘宾元, 张莉 一种N-取代酰亚胺的制备方法 专利公开号CN1724518A （授权，ZL2005 1 0014591.9） 3. 刘宾元, 闫卫东, 章文军, 王亚琴, 曲佳燕, 张莉 合成降冰片烯与马来酸酐共聚物的方法，专利公开号 CN101045775 专利申请号200710057296.0 4. 刘宾元, 闫卫东, 李杨, 王晓亚, 曲佳燕, 张莉 含脂环基的聚N-取代降冰片烯酰亚胺及其制备方法，专利申请号CN: 200710057398.2 专利公开号：CN 101050254A 5. 刘宾元，刘宝兴，曲佳燕，张旭，杨敏 一种聚醚醚酮类聚合物及其制备方法，专利申请号200910068352.X 6. 刘宾元，赵鑫，高延浩，张莉，曲佳燕，杨敏 用于二氧化碳与环氧化合物共聚的催化剂及其制备方法和应用，专利申请号200910068351.5 7. 闫卫东,杨 敏, 刘盘阁, 刘宾元，张 旭，胡文艳，郝小宇，沈晓莉 用于制备支化聚乙烯的多米诺催化体系及其应用方法，专利公开号CN101220107 （专利申请号200710058763.1） 8. 闫卫东，杨 敏，刘宾元，郝小宇，刘盘阁，温丽芳，程 曼 以乙烯为唯一单体制备支化聚乙烯的茂金属多米诺催化体系及其应用，专利公开号CN101392036 （专利申请号200810152817.5） 9. 闫卫东，张宁宁，任合刚，张国虹，刘宾元，杨 敏，张 旭 用于合成线形低密度聚乙烯的钛/钒双金属催化剂及其制备方法和应用，专利公开号CN101220107（专利申请号200810052253.8） 论文 1. Binyuan Liu, Xiaojiang Zhao, Xianhong Wang and Fosong Wang "Copolymerization of Carbon Dioxide and Propylene Oxide with Ln(CCl3COO)3-Based catalyst: the Role of Rare Earth Compound in the Catalytic System",J. Polym. Sci, Part A Polym Chem. 2001, 39(16), 2751-2754.（SCI: 456XU; EI:2001386654909） 2. Binyuan Liu, Xiaojiang Zhao, Xianhong Wang and Fosong Wang "Copolymerization of Carbon Dioxide and Propylene oxide with Neodymium-Based Coordination Catalyst", Polymer. 2003，44（6），1803-1808 (SCI: 650JW; EI: 2003107384646) 3. Binyuan Liu, Xiaojiang Zhao, Xianhong Wang and Fosong Wang "Thermal Degradation Kinetics of Poly (propylene carbonate) Obtained from Copolymerization of Carbon Dioxide andPropylene Oxide",J. Appl. Polym. Sci. 2003, 90(4), 947-953 (SCI:717LQ; EI 2003397651064) 4. Binyuan Liu, Zhixin Xue, Lu Liu, Li Zhang, Fang Liu “Modification and Characterization of Poly (ethylene-co-vinyl alcohol) by Glycosidations Reaction”,J Appl Polym Sci, 2006, 102 (1), 227-232. （SCI：077QO;EI：064110167651） 5. Binyuan Liu, Chunying Tian, Li Zhang, Weidong, Yan, Wenjun Zhang “Copolymerization of Carbon Dioxide and Cyclohexene Oxide Using Zinc b-ketoiminato Complexes: Investigating the Influence of Electron Struacture of Zinc b-ketoiminato Complexes on the Catalytic Activity and Resultant Copolymer Properties”, J Polym Sci, Part A: Polym Chem, 2006，44，6243-6251. (SCI：096HR；EI：064510224441) 6. 刘宾元，王新利，张莉，闫卫东，李晓然, 丁酰化壳聚糖的制备及结构性能表征, 高分子科学与工程，2007，23，130-133. (EI：072710691130) 7. Binyuan Liu, Yang Li, Li Zhang, Weidong Yan, Shuhuan Yao “Study on Thermal Degradation Kinetics of Poly (N-adamantyl-exo-nadimide) Synthesized by Addition Polymerization”, J Appl Poly Sci , 2007, 103, 3003-3009. (SCI：129YD; EI：071010472256) 8. Binyuan Liu, Yang Li, Boo-Gyo Shin, Do Yeung Yoon, IL Kim, Li Zhang, Weidong Yan “Pd (II)-Catalyzed Vinyl Addition Polymerization of Novel Functionalized Norbornene Bearing Dimethyl Carboxylate Groups", J Polym Sci, Part A: Polym Chem, 2007, 45,3391-3399. (SCI：189XK; EI：073210757526) 9. Binyuan Liu, Yang Li, IL Kim, Boo-gyo Shin, Do Yeung Yoon, Li Zhang, Rongqin Ji, Weidong Yan “Thermal Characterization and Thermal Degradation of Poly (norbornene-2, 3-dicarboxylic acid dialkyl ester)s Synthesized by Vinyl Addition Polymerization”, Polym Degrad Stab, 2007, 92, 868-875. (SCI：172SD;EI：071810582720) 10. Binyuan Liu, Haiqing, Li, Weidong Yan, Chang-Sik IL Kim*. “Ring-opening Polymerization of e-Caprolactone and Cyclohexene Oxide Initiated by Aluminum b-Ketoamino Complexes: Steric and Electronic Effect of 3-Position Substituents of the Ligands on Polymerization”, Macromol Res, 2008, 6(5), 441- 445. (SCI：335AU) 11. Binyuan Liu, Yang Li, Anu Stell Mathews, Yige Wang, Weidong Yan, Sinoj Abraham, Chang-Sik Ha, Daewon Park, IL Kim*. “Synthesis of Vinyl-type Functionalized Polynorbornene with Cyclic Pendant Imide Side Groups Using Palladium-Based Catalyst for Low Dielectric Constant Materials”, React Function Polym, 2008，68, 1619-1624. (SCI: 386HJ) 12. Binyuan Liu*, Xiaoya Wang, Yige Wang, Weidong Yan, Huanrong Li, Il Kim, “Palladium(II) Catalyzed Addition Polymerizations of Nadimides with Linear Alkyl and Alicyclic Pendant Groups”, React Function Polym, 2009, doi10.1016/j.reactfunctpolym.2009.04.002，已录用 13. 刘宾元*，王晓亚，王弋戈，闫卫东，“降冰片烯酰亚胺的合成与表征”，化学试剂，2009，已录用 14. 刘宾元*，高延浩，赵鑫，闫卫东“新型水杨醛衍生物的合成”，化学试剂2009，已录用 15. 毛彦科, 刘宾元* , 闫卫东“BP/THF引发体系引发降冰片烯与马来酸酐可见光自由基共聚合”化工新型材料，2009，已录用 16. Min Yang, Binyuan Liu, Luhai Wang, Hegang Ren, Wenyan Hu, Lifang Wen, Weidong Yan*，“Novel tandem catalytic system of β-diketonate zirconium/two different cocatalysts for preparing branched polyethylene”, Catal Commun, 2009, doi: 10.1016/j.catcom.2009.03.014已录用 17. Yige Wang, Huanrong Li*, Binyuan Liu, Quanying Gan, Qinglin Dong, Gion Calzaferri, Zheng Sun, “Fabrication of oriented zeolite L monolayer via covalent molecular linkers”,J Sold Stat Chem, 2008, 181, 2469-2472.( SCI: 351HR; EI: 20083711546849) 18. Boo-Gyo Shin, Tai-Yon Cho, Do Y. Yoon, Binyuan Liu “Structure and Properties of Polynorbornene Derivatives. Poly(norbornene dicarboxylic acid dialkyl ester)s and Poly(norbornene dimethyl dicarboxylate)s”, Macromol Res, 2007, 15, 185 (SCI:155YF) 19. Huanrong Li, Yige Wang, Wenjun Zhang, Binyuan Liu, Gion Calzaferri "Fabrication of oriented zeolite L monolayers employing luminescent perylenediimide-bridged silsesquioxane precursor as the covalent linker", Chem Commun, 2007, 2853-2854.(SCI: 186GM) 20. Peng Liu, Huanrong Li*, Yige Wang, Binyuan Liu, Wenjun Zhang, Yanji Wang, Weidong Yan, Hongjie Zhang , Ulrich Schubert. “Europium complexes immobilization on titania via chemical modification of titanium alkoxide”, J Mater Chem, 2008, 18, 735 – 737. (SCI: 259IP；EI: 080711093590) 21. Yige Wang, Huanrong Li*, Wenjun Zhang, Binyuan Liu, “Luminescene properties of nanozeolite L grafted with terbium organic complex”, Mater Lett, 2008, 62(17-18), 3167-3170. (SCI: 155YF；EI: 082011253168) 22. 胡文艳, 杨敏, 赵辛, 刘宾元, 郝小宇, 闫卫东* “β-二酮锆/AlEt2C/MAO催化乙烯原位共聚合成支化聚乙烯(Synthesis of Branched Polyethylene from Ethylene via in situ Copolymerization Catalyzed by β-Diketonate Zirconium/AlEt2Cl/MAO)”高等学校化学学报(Chemical Journal of Chinese Universities), 2008, 29(2),430-432. (SCI: 262HO) 23. Xu Zhang, Weidong Yan*, Huifang Yang, Binyuan Liu, Pange Liu“Functionalization of Three-Dimensionally Ordered Macroporous Cross-Linked Polystyrene by Atom-Transfer Radical Polymerization of Hydroxyethyl Methacrylate and Subsequent Derivatization” J Polym Sci, Part A: Polym Chem, 2008, 46, 7950-7959. ( SCI: 383WP; EI: 20085211808698) 24. Xu Zhang, Weidong Yan*, Huifang Yang, Binyuan Liu, Haiqing Li “Gaseous Infiltration Method for Preparation of Three-Dimensionally Ordered Macroporous Polyethylene”, Polymer, 2008, 49, 5446-5451.( SCI: 380JU; EI: 20084711719416) 25. Yige Wang, Li Wang, Huanrong Li*, Peng Liu, Dashan Qin, Binyuan Liu, Wenjun Zhang, Ruiping Deng, Hongjie Zhang, “Synthesis and luminescene properties of hybrid organic-inorganic transparent titanin thin film actived by in-situ formed lanthanide complexes”, J Sold Stat Chem, 2008, 181, 562-566. (SCI: 273JB; EI: 080911122938) 26. Huanrong Li*, Huifang Shao, Yige Wang, Dashan Qin, Binyuan Liu, Wenjun Zhang, Weidong Yan. “Soft material with intense photoluminescence obtained by dissolving Eu2O3 and organic ligand into a task-specific ionic liquid”, Chem. Commun., 2008, 5209-5211(SCI: 365LH) 27. Xu Zhang, Weidong Yan*, Huifang Yang, Binyuan Liu, Pange Liu “Preparation and Characterization of Pore Wall-Functionalized Three-dimensionally Ordered Macroporous Syndiotactic Polystyrene”, Polym Eng Sci，2009, 49, 223-228. (SCI: 398BB; EI: 20090911923250) 28. Min Yang, Wei-dong Yan*, Xiao-yu Hao, Binyuan Liu, Li-fang Wen, Pan-ge Liu “Tandem Catalytic Systems: One Catalyst Combined with Two Different Activators for Preparing Branched Polyethylene with Ethylene as Single Monomer” Macromolecular, 2009, 42, 905-907.（SCI: 408IW） 29. Weidong Yan*, Xiaoyu Hao, Min Yang, Binyuan Liu, Pange Liu “Preparation of Branched Polyethylene by A Novel Tandem Catalytic System: rac-Et(Ind)2ZrCl2/AlEt2Cl/MAO”, J Polym Sci, Part A: Polym Chem 2009, 47,1966-1970. 30. Xu Zhang, Weidong Yan*, Huifang Yang, Binyuan Liu, Pange Liu “Graft Polymerization from Pore Wall of Three-dimensionally Ordered Macroporous Cross-linked Polystyrene via Atom Transfer Radical Polymerization”, Eur Polym J doi:10.1016/j.eurpolymj.2009.01.033，已录用 31. 张宁宁，刘宾元，王卫峰，任合刚，闫卫东*，Z-N催化剂内给电子体作用机理的研究进展，合成树脂与塑料，2009, 26, 73-76. 32. 闫卫东*，刘宾元，张旭，张莉，现代条件下高校教师教学基本功的内容浅析，河北工业大学学报(成人教育学院学报)，2008，23(4), 19-22. 会议论文 1. Binyuan Liu, Xiaojiang Zhao, Xianhong Wang, Daqing Zhao and Fosong Wang "Synthesis, Structure and Properties of Carbon Dioxide Copolymer" (Oral presentation) The Polymer Division Chinese Chemical Society, 6th Pacific Polymer Conference, Guang Zhou: Preprints, 1999, 67. 2. 刘宾元， 全志龙，谢东， 赵晓江，王献红， 王佛松， 张志豪，莫志深 稀土催化剂下可生物降解的二氧化碳共聚物聚丙撑碳酸酯的合成， 材料年会， 北京，2000，1001 3. Binyuan Liu, Xiaojiang Zhao, Xianhong Wang and Fosong Wang “Copolymerization of Carbon Dioxide and Propylene Oxide with Ln(CCl3COO)3-based catalyst: the Role of Rare Earth Compound in the Catalytic System”(Oral presentation) Chinese-Russ Symposium Russ，2001.3 4. Binyuan Liu, Boogyo Shin, Do Yeung Yoon “Synthesis and Polymerization of Norbornene Derivatives” Annual meeting of the Polymer Society of Korea，Gunshan，2002，27(2)，234 5. Binyuan Liu, et al “Vinyl-type Polymerization of Norbornene-exo-2,3-dimethyl Carboxylate”, Annual meeting of the Polymer Society of Korea, 2003, October, Poster. 6. Binyuan Liu, et al , “Synthesis and Structure-Property Relationships of Poly(norbornene dicarboxylic acid dialkyl esters) and Poly(norbornene dimethyl carboxylates)”, Annual meeting of the Polymer Society of Korea, 2004, October. 7. Binyuan Liu, Do Yeung Yoon“降冰片烯衍生物的制备及及加成聚合反应的研究”全国高分子材料科学与工程研讨会，上海，2004，15 8. Binyuan Liu, Ai Desheng, Li Yabin, Ji Rongqin, Liu Pange. “Surface-confined radical chain transfer polymerization of methyl methacrylate on zirconium oxide nanoparticle”, 40th International Unin of Pure and Apllied Chemistry (IUPAC) Congress, Beijing, Preprint: 2005. 9. Binyuan Liu, Chunying Tian. “Highly Effective Zinc Enolimine Complex-based Catalyst for the Alternating Copolymerization of Carbon Dioxide and Cyclohexene Oxide”, IPMEC2005, Shanghai, 2005 10. 刘宾元，田春英， 章文军， 王振， 新型二氧化碳与环氧化合物共聚催化剂，2005年全国高分子学术论文报告会，北京 11. 刘宾元， 薛志欣，刘芳，刘璐，糖苷化反应修饰聚（乙烯-乙烯醇），2005年全国高分子学术论文报告会，北京 12. Li yang,Liu Binyuan, Zhang li, Yan weidong, Al desheng, “palladium(II)-based catalyst for the vinyl addition polymerization of norbornene derivatives with ester groups”, 4th East Asian Polymer Conference, May 21-31, 2006, Tianjin, China, P231 13. Binyuan Liu,Yang Li,Weidong Yan,Rongqin Ji,Pange Liu, “Study on Thermal Properties and Thermal Decomposition Kinetics Heat-Resistant Vinyl-type Poly(nadimides)” 4th International Symposium High-tech Polymer Materials Synthesis,Characterization and Applications, May 14-20, 2006, Beijing, China, P116 14. Binyuan Liu,Yang Li, Weidong Yan, Deshen Ai,(η3-allyl)palladium(II) catalysts for addition polymerization of norbornene imide, International Symposium on Polymer Chemistry Preprints, June 7-11, 2006, Dalian, China, P348 15. Binyuan Liu, IL Kim, Daewon Park “ Effect of 3 substitutents on backbone of b-ketoiminato ligands of zinc b-ketoiminato complexes on the copolymerization of carbon dioxide and cyclohexene oxide” Korea-Japan Joint Symposium on Polymers-Young Scientist Exchange Busan, Korea, October 10, 2006 P53 16. Binyuan Liu, Yang Li, IL Kim, Weidong Yan. “Functionalized Norbornene with Imide Groups Vinyl Polymerization by Pd (II) Complexes with Weak Counter Ions” The 11th Korea-Japan Symposium on Catalyst, May 21-23, 2007, Seoul, Korea. 17. Binyuan Liu, Li Zhang, Yang Li, Yige, Wang, Anu Stella Mathews, Chang-Sik Ha, IL Kim Wenjun Zhang, Weidong Yan “Low Dielectric Constant Vinyl-type Polynorbornene Dicarboximide with Bulky Pendant Groups”3rd INTERNATIONAL SYMPOSIUM ON ENGINEERING PLASTICS, August 19-24, 2007, Urumqi, China 18. Binyuan Liu, Li Zhang, Yaqin, Wang, Wenjun, Zhang, Weidong Yan “Synthesis of 193nm Photoresist Norbornene and Maleic Anhydride Copolymer Via Free Radical Polymerization Using Oxygen as Promoter”3rd INTERNATIONAL SYMPOSIUM ON ENGINEERING PLASTICS, August 19-24, 2007, Urumqi, China 19. Li Zhang, Yang Li, Binyuan Liu, Yige, Wang, Weidong Yan “The Soluble and Processible Functionalized Polynorbornene with Dimethyl Carboxylate Groups”3rd INTERNATIONAL SYMPOSIUM ON ENGINEERING PLASTICS, August 19-24, 2007, Urumqi, China 20. Binyuan Liu, Xiaoya Wang, Pei Wu, Weidong Yan, Addition Polymerizationof Functionalized Norbornene: Effects of Pedant Imide Group on the Reactivity and Resulting Polymer Properties. International Symposium on Polymer Chemistry, PC2008, June15-19，2008，HeFei, China. P 129 (oral present) 21. YAN Weidong*, YANG Min, LIU Binyuan, HU Wenyan, HAO Xiaoyu. Synthesis of Branched Polyethylene from Ethylene by Tandem Catalysis of β-Diketonate Zirconium /AlEt2Cl/ MAO. International Symposium on Polymer Chemistry PC2008, June15-19，2008，HeFei, China. P328